@article{oai:kochi.repo.nii.ac.jp:02000257,
 author = {Fujishiro, Fumito and Oshima, Natsumi and Sakuragi, Tokio and Oishi, Masatsugu},
 journal = {Journal of Solid State Chemistry},
 month = {May},
 note = {To understand the B-site mixing effect in perovskite-type SrFe1−xCoxO3−δ, we evaluated the relationship between the oxygen desorption properties and the reduction behavior of Fe and Co ions using thermogravimetry and in-situ X-ray absorption spectroscopy. The valence states of Fe and Co ions were estimated to be 3.56+ and 3.27+, respectively, which remained constant with changes in composition. Maximum oxygen desorption occurred at x = 0.2 below 800 °C. As temperature was increased and oxygen was released, a relationship was observed between the valence and coordination number changes of each B-site ion; these changes were more pronounced for the Fe ions than for the Co ions. In SrFe1−xCoxO3−δ samples, oxygen adjacent to Fe ions was released more readily than oxygen adjacent to Co ions. This conclusion is supported by the electronic states of the two B-site ions. These results are important for the design of new oxygen storage materials.},
 title = {Oxygen desorption properties of perovskite-type SrFe1−xCoxO3−δ: B-site mixing effect on the reduction properties of Fe and Co ions},
 volume = {312},
 year = {2022}
}